Greatest
From Ultipedia
A greatest is a play that involves jumping from within the field of play to beyond the sidelines in order to catch the disc and then releasing a throw before landing (or touching anything out of bounds).
It is typically an unplanned desperate move, but when successful it can be spectacular.
[edit] Explanation
As a player is considered 'in bounds' until touching something that is 'out of bounds' a player still in the air, but outside the field of play is still considered 'in bounds' if they jumped from within the confines of the field of play.
[edit] The name
This move is called the Greatest, because if you can do it, you are "The Greatest."